Industrial Health

profilescoobizzle
UnitIII_SDS_Paint.pdf

SAFETY DATA SHEET Revision date 25-Apr-2015 Version 2

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier Product Code ALS5N0035

Product Name EARTH VEIN

Other means of identification No information available

Recommended use of the chemical and restrictions on use Paint, Coatings

Details of the supplier of the safety data sheet See section 16 for more information

The Valspar Corporation PO Box 1461 Minneapolis, MN 55440

E-mail address [email protected]

Emergency telephone number United States of America 1-888-345-5732 American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924

Section 2: HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label elements

Product Code ALS5N0035

HAZARD STATEMENTS

Page 1 / 8

Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)

AGHS - USA OSHA SDS

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No weight-% Carbon black 1333-86-4 1 - 3

Titanium dioxide 13463-67-7 0.1 - 0.3

*The exact percentage (concentration) of composition has been withheld as a trade secret.

Section 4: FIRST AID MEASURES

First Aid Measures

General advice Get medical advice/attention if you feel unwell.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Skin Contact Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.

Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell.

Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Most important symptoms and effects, both acute and delayed

Symptoms No information available.

Indication of any immediate medical attention and special treatment needed

PREVENTION Do not handle until all safety precautions have been read and understood.

RESPONSE Get medical advice/attention if you feel unwell.

Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

STORAGE Store in a closed container.

DISPOSAL Dispose of contents/containers in accordance with local regulations.

HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) Not applicable. May form combustible dust concentrations in air.

Product Code ALS5N0035

OTHER HAZARDS Not applicable.

Page 2 / 8 AGHS - USA OSHA SDS

UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.

Note to physicians Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

Suitable extinguishing media Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.

Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet

Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes.

Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Remove all sources of ignition. Do not breathe dust.

For emergency responders Use personal protection recommended in Section 8.

Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).

Section 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.

General Hygiene Considerations Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.

Incompatible materials Alcohols. Amines.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Product Code ALS5N0035

Page 3 / 8 AGHS - USA OSHA SDS

Control parameters

Exposure Limits If S* appears in the OEL table, it indicates this chemical contains a skin notation.

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Carbon black 1333-86-4

TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 IDLH: 1750 mg/m3

TWA: 3.5 mg/m3

TWA: 0.1 mg/m3 Carbon black in presence of Polycyclic aromatic

hydrocarbons PAH Titanium dioxide

13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3

Appropriate engineering controls

Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not breathe dust.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at neck and wrists through contact with the powder are avoided.

Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.

Respiratory protection In case of inadequate ventilation wear respiratory protection.

Thermal Protection No information available

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state powder Appearance No information available Odor Odorless Color brown Odor Threshold No information available pH value No information available Melting point/freezing point No information available Boiling point / boiling range No information available °C / °F flash point 510 °C / 950 °F evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air

Upper flammability limit: No information available Lower flammability limit: No information available

Vapor Pressure No information available vapor density No information available Density (lbs per US gallon) 10.28

Product Code ALS5N0035 Page 4 / 8

AGHS - USA OSHA SDS

specific gravity 1.23 Solubility(ies) No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available

Other information

Section 10: STABILITY AND REACTIVITY

Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of Hazardous Reactions None under normal processing.

Hazardous polymerization None under normal processing.

Conditions to avoid Heat, flames and sparks.

Incompatible materials Alcohols. Amines.

Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.

Section 11: TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Eye contact Not applicable Skin Contact Not applicable Ingestion Not applicable Inhalation Not applicable

Numerical measures of toxicity - Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Carbon black 1333-86-4

- - -

Titanium dioxide 13463-67-7

> 10000 mg/kg ( Rat ) - -

Numerical measures of toxicity - Product Information

UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon black is thought to occur from use in paints since the pigment is bound to other materials. Chemical Name ACGIH IARC NTP OSHA

Carbon black 1333-86-4

A3 Group 2B X

Product Code ALS5N0035 Page 5 / 8

AGHS - USA OSHA SDS

Titanium dioxide 13463-67-7

Group 2B X

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen. IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present.

Skin corrosion/irritation Not applicable Serious eye damage/eye irritation Not applicable Skin sensitization Not applicable Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Not applicable Reproductive Toxicity Not applicable Specific target organ toxicity (single exposure)

Not applicable

Specific target organ toxicity (repeated exposure)

Not applicable

Aspiration hazard Not applicable

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity Environmental precautions Prevent product from entering drains.

Persistence and degradability No information available

Bioaccumulation No information available

Mobility No information available

Other adverse effects No information available

Section 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned.

Section 14: TRANSPORT INFORMATION

14.5 Environmental hazard Not applicable

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available

Section 15: REGULATORY INFORMATION International Inventories

DOT IMDG IATA 14.1 UN/ID no Not regulated Not regulated Not regulated 14.2 Proper shipping name

14.3 Hazard Class 14.4 Packing Group

Product Code ALS5N0035

14.6 Special Provisions

Page 6 / 8 AGHS - USA OSHA SDS

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt from listing

DSL - Canadian Domestic Substances List Not all components are listed or exempt from listing

US Federal Regulations

SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No

US State Regulations

Rule 66 status of product Not photochemically reactive.

U.S. EPA Label information EPA Pesticide registration number Not applicable

U.S. State Right-to-Know Regulations

Chemical Name .

Proprietary Non-Hazardous Ingredient - Proprietary CAS .

Proprietary Non-Hazardous Ingredient - Proprietary CAS .

Proprietary Inert .

Carbon black 1333-86-4

.

Iron oxide (Fe2O3) 1309-37-1

.

Section 16: OTHER INFORMATION

HMIS Health hazards 0 Flammability 1 Physical hazards 0 Personal Protection X

Supplier Address

Prepared By Product Stewardship

Product Code ALS5N0035

Revision date 25-Apr-2015

Page 7 / 8

Revision Note No information available

AGHS - USA OSHA SDS

Valspar Coatings 10300 Claude Freeman Dr. Charlotte, NC 28262 704-548-2820

Valspar Powder Coatings 13129 Harland Dr. NE Covington, GA 30014 770-784-4140

Disclaimer The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.

End of Safety Data Sheet

Product Code ALS5N0035 Page 8 / 8

AGHS - USA OSHA SDS