Industrial Health
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SAFETY DATA SHEET Revision date 25-Apr-2015 Version 2
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifier Product Code ALS5N0035
Product Name EARTH VEIN
Other means of identification No information available
Recommended use of the chemical and restrictions on use Paint, Coatings
Details of the supplier of the safety data sheet See section 16 for more information
The Valspar Corporation PO Box 1461 Minneapolis, MN 55440
E-mail address [email protected]
Emergency telephone number United States of America 1-888-345-5732 American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924
Section 2: HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Product Code ALS5N0035
HAZARD STATEMENTS
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Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
AGHS - USA OSHA SDS
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No weight-% Carbon black 1333-86-4 1 - 3
Titanium dioxide 13463-67-7 0.1 - 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General advice Get medical advice/attention if you feel unwell.
Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
PREVENTION Do not handle until all safety precautions have been read and understood.
RESPONSE Get medical advice/attention if you feel unwell.
Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
STORAGE Store in a closed container.
DISPOSAL Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) Not applicable. May form combustible dust concentrations in air.
Product Code ALS5N0035
OTHER HAZARDS Not applicable.
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UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.
Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet
Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes.
Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Remove all sources of ignition. Do not breathe dust.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13).
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.
General Hygiene Considerations Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Incompatible materials Alcohols. Amines.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Product Code ALS5N0035
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Control parameters
Exposure Limits If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Carbon black 1333-86-4
TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in presence of Polycyclic aromatic
hydrocarbons PAH Titanium dioxide
13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
Appropriate engineering controls
Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not breathe dust.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin and body protection Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at neck and wrists through contact with the powder are avoided.
Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Thermal Protection No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state powder Appearance No information available Odor Odorless Color brown Odor Threshold No information available pH value No information available Melting point/freezing point No information available Boiling point / boiling range No information available °C / °F flash point 510 °C / 950 °F evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air
Upper flammability limit: No information available Lower flammability limit: No information available
Vapor Pressure No information available vapor density No information available Density (lbs per US gallon) 10.28
Product Code ALS5N0035 Page 4 / 8
AGHS - USA OSHA SDS
specific gravity 1.23 Solubility(ies) No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Alcohols. Amines.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact Not applicable Skin Contact Not applicable Ingestion Not applicable Inhalation Not applicable
Numerical measures of toxicity - Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Carbon black 1333-86-4
- - -
Titanium dioxide 13463-67-7
> 10000 mg/kg ( Rat ) - -
Numerical measures of toxicity - Product Information
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon black is thought to occur from use in paints since the pigment is bound to other materials. Chemical Name ACGIH IARC NTP OSHA
Carbon black 1333-86-4
A3 Group 2B X
Product Code ALS5N0035 Page 5 / 8
AGHS - USA OSHA SDS
Titanium dioxide 13463-67-7
Group 2B X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen. IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present.
Skin corrosion/irritation Not applicable Serious eye damage/eye irritation Not applicable Skin sensitization Not applicable Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Not applicable Reproductive Toxicity Not applicable Specific target organ toxicity (single exposure)
Not applicable
Specific target organ toxicity (repeated exposure)
Not applicable
Aspiration hazard Not applicable
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity Environmental precautions Prevent product from entering drains.
Persistence and degradability No information available
Bioaccumulation No information available
Mobility No information available
Other adverse effects No information available
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned.
Section 14: TRANSPORT INFORMATION
14.5 Environmental hazard Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
Section 15: REGULATORY INFORMATION International Inventories
DOT IMDG IATA 14.1 UN/ID no Not regulated Not regulated Not regulated 14.2 Proper shipping name
14.3 Hazard Class 14.4 Packing Group
Product Code ALS5N0035
14.6 Special Provisions
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TSCA - United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt from listing
DSL - Canadian Domestic Substances List Not all components are listed or exempt from listing
US Federal Regulations
SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No
US State Regulations
Rule 66 status of product Not photochemically reactive.
U.S. EPA Label information EPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name .
Proprietary Non-Hazardous Ingredient - Proprietary CAS .
Proprietary Non-Hazardous Ingredient - Proprietary CAS .
Proprietary Inert .
Carbon black 1333-86-4
.
Iron oxide (Fe2O3) 1309-37-1
.
Section 16: OTHER INFORMATION
HMIS Health hazards 0 Flammability 1 Physical hazards 0 Personal Protection X
Supplier Address
Prepared By Product Stewardship
Product Code ALS5N0035
Revision date 25-Apr-2015
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Revision Note No information available
AGHS - USA OSHA SDS
Valspar Coatings 10300 Claude Freeman Dr. Charlotte, NC 28262 704-548-2820
Valspar Powder Coatings 13129 Harland Dr. NE Covington, GA 30014 770-784-4140
Disclaimer The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.
End of Safety Data Sheet
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AGHS - USA OSHA SDS